倾斜入射下的单截面平面度绝对检验

针对大尺寸光学平面的直线度的纳米级测量精度需求，提出了倾斜入射下单截面平面度绝对检验方法，实现了对超过相移干涉仪口径的长平晶绝对检验。利用棱镜转向实现倾斜入射角度的精密预标定，棱镜标定角度的精度高于圆光栅和图像分析等方法，可提高测量不确定度到0.0042 μm。对比了常规三面互检绝对检验结果与本方法的差异，在相同尺寸下，直线度误差仅为1.2 nm。在确认标定反射镜位置后，整个倾斜入射的干涉图调整过程将被完全集中到待测长平晶的工作面上，不需要再对反射平晶进行操作。调整长平晶时各个维度的操作互不干涉，可快速简便地得到测量结果。     

配分工艺对中碳Ti-Mo高强Q&P钢组织和性能的影响

摘要：采用盐浴实验、扫描电镜、透射电镜、拉伸实验和磨损实验等手段，研究了配分工艺对中碳Ti Mo钢组织和性能的影响，分析了不同配分工艺处理下的组织演变和性能变化。结果表明，显微组织主要由回火马氏体、渗碳体、(Ti，Mo)C粒子组成。随着配分时间的延长和配分温度的升高，板条马氏体数量减少，马氏体板条厚度增加，边界钝化。此外，随着配分温度从310℃提高至400℃，抗拉强度、硬度和低温冲击韧性同时下降，分别降低约250MPa、56HV和15J。最后，Ms以下温度配分（310℃）试样的耐磨损性能明显优于Ms以上温度配分（400℃）试样。Ms以下温度配分试样磨损表面形貌以塑性变形为主，Ms以上温度配分试样磨损表面以犁沟为主。     

Microstructure and mechanical behavior of laser aided additive manufactured low carbon interstitial Fe49.5Mn30Co10Cr10C0.5 multicomponent alloy

Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0％respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2％were observed for fractured sample tested at-40℃,compared with 6.3％in fractured room temperature sample.     

梯度铝蜂窝夹芯板的力学行为

梯度分层铝合金蜂窝板是一种有效的吸能结构,本工作在梯度铝蜂窝结构的基础上根据梯度率的概念,通过改变蜂窝芯层的胞壁长度,设计了4种质量相同、梯度率不同的铝蜂窝夹芯结构。通过准静态压缩实验,并结合非线性有限元模拟准静态及冲击态下梯度铝蜂窝夹芯结构的变形情况及其力学性能,分析对比了相同质量下梯度铝蜂窝夹芯结构在准静态下的变形模式以及冲击载荷下分层均质蜂窝结构和不同梯度率的分层梯度蜂窝结构的动态响应和能量吸收特性。结果表明:在准静态压缩过程中,铝蜂窝梯度夹芯板的变形具有明显的局部化特征,蜂窝芯的变形为低密度优先变形直至密实,层级之间的密实化应变差随芯层密度的增大而逐渐减小;在高速冲击下,梯度蜂窝板并非严格按照准静态过程中逐级变形直至密实,而是在锤头冲击惯性及芯层密度的相互作用下整体发生的线弹性变形、弹性屈曲、塑性坍塌及密实化;另外,在本工作所设计的梯度率中,当梯度率为γ₁=0.0276时,梯度蜂窝夹芯板的吸能性达到最好,相较于同等质量下的均质蜂窝夹芯板,能量吸收提高了10.63%。     

Electrical and magnetic properties of double perovskite: Y2CoMnO6

In this communication, the structural, micro-structural, dielectric, electrical, magnetic, and leakage-current characteristics of a double perovskite (Y₂CoMnO₆) ceramic material have been reported. The material was synthesized via a high-temperature mixed-oxide route. The compound crystallizes in a monoclinic structure which is confirmed from preliminary X-ray structural study. The morphological study by using scanning electron micrograph reveals the almost homogeneous distribution of grains throughout the surface of the sample. The nature of frequency-dependence of dielectric constant has been described by the Maxwell-Wagner model. The occurrence of a dielectric anomaly in the temperature dependence of dielectric permittivity study demonstrates the ferroelectric-paraelectric phase transition in the material. From the Nyquist plots, we found the existence of both grain and grain boundary effects. The frequency dependence of conductivity was studied by the Jonscher’s Power law, and the conduction phenomenon obeys the large overlapping polaron tunneling model. By using the Arrhenius equation, the activation energy has been calculated which is nearly equal to the energy required for the hoping of the electron. Both impedance and conductivity analysis demonstrate that the sample exhibits negative temperature coefficient of resistance (NTCR) properties indicating the semiconducting type of material at high temperatures. The anti-ferromagnetic character of the material is observed from the nature of magnetic hysteresis loop. The leakage current analysis suggests that the conduction process in the material follows the space charge limited conduction phenomenon. Such material will be helpful for modern electronic devices and spintronic applications.     

Improvement of mechanical property and corrosion resistance of Mg-Zn-Nd alloy by bi-direction drawing

Mg-Zn-Nd alloy is a promising biodegradable metal material for surgical staples during the reconstruc-tion of digestive tract due to its good biocompatibility and suitable mechanical properties.However,its deformation property and corrosion resistance should be improved to make better safety and effective-ness of staples.In the present study,bi-direction drawing was adopted to maintain the initial texture characteristics,and improve mechanical property and corrosion resistance of Mg-2Zn-0.5Nd alloy.The results showed that the microstructure after bi-direction did not change too much,but the texture could maintain its initial characteristics.The ductility of the alloy with 60 ％ accumulative area reduction after bi-direction drawing was increased by 70 ％,indicating that an outstanding deformation property of Mg-Zn-Nd alloy can be obtained by bi-direction drawing.The corrosion resistance was also improved after bi-direction drawing compared with that under single direction drawing.     

Review on development of metal/ceramic interpenetrating phase composites and critical analysis of their properties

Metal/ceramic composites are in high demand in several industries because of their superior thermo-mechanical properties. Among various composite types, the interpenetrating phase composites (IPCs) with percolating metallic and ceramic phases offer manifold benefits, such as a good combination of strength, toughness, and stiffness, very good thermal properties, excellent wear resistance, as well as the flexibility of microstructure and processing route selection, etc. The fabrication of metal/ceramic IPCs typically involves two steps - i) processing of an open porous ceramic body, and ii) infiltration of metallic melt in the pores to fabricate the IPC. Although significant progress has been made in recent years for developing both porous ceramics and melt infiltration methods, to the best of the knowledge of the authors, no review article summarizing all the aspects of processing and properties of IPCs has been published till date. This review article is aimed at filling this gap. Starting with a brief introduction about the current status and applications of IPCs, the various processing routes for fabricating open porous ceramic preforms and melt infiltration techniques have been discussed. Subsequently, the data available for various important physical, mechanical, and thermal properties for IPCs have been critically analyzed to thoroughly understand their dependence on various structural and processing parameters. To compare the properties of IPCs with other relevant materials, seven different Ashby material property maps have been used, and the domains for IPCs have been created in them. For each map, the concept of material indices has been employed to critically discuss how IPCs perform in relation to other material classes for various optimum design conditions. Finally, a detailed future outlook for further research on IPCs has been provided.     

Mathematical law of size effect on the flexural property of ceramics

Brittle materials generally exhibit size effects, and the mechanical properties of these materials degrade significantly with an increase in size. However, the mathematical law governing the attenuation degree of mechanical properties with the increase in size is still unknown. In this study, maximum loads of differently sized ceramic test strips were subjected to three point bending tests under two working conditions of equal spans and span amplifications, respectively. Subsequently, the theoretical maximum loads of materials were calculated using the finite element method (FEM). By calculating the difference between the calculated values and the actual maximum loads, the attenuation of mechanical properties of ceramic samples were observed. The results show that the theoretical mechanical properties and the performance attenuation caused by the size effect tend to increase according to the following equation: y=ax³+bx²+cx+d. Therefore, mechanical properties and performance attenuation of any sample exhibiting a size within the experimental range can be predicted by a mathematical law, which was obtained through mechanical tests results of four samples with different sizes. The obtained mathematical law holds great significance for predicting the mechanical properties of materials under size effects.     

Novel Bi4O5Br2/MnxZn1-xFe2O4 magnetic composite with an enhanced photodegradation activity and excellent recyclability

Bi₄O₅Br₂/Mn_xZn_1-xFe₂O₄ nanocomposites with impressive photocatalytic and recyclability properties were synthesised using a microemulsion method. In addition to the photocatalytic effect, the crystal structure and morphology, photoelectrochemical characteristics, magnetic effect and photocatalytic mechanism of Bi₄O₅Br₂/Mn_xZn_1-xFe₂O₄ were also investigated. As the best sample, the removal rate of the Bi₄O₅Br₂/Mn_xZn_1-xFe₂O₄ photocatalyst with 7.5 wt% Mn_xZn_1-xFe₂O₄ to rhodamine B (RhB) reached up to 99.4% within 60 min. The enhanced photocatalyst activity was mainly attributed to the type-II heterojunction formed between Bi₄O₅Br₂ and Mn_xZn_1-xFe₂O₄, which not only optimised the energy band structure, but also led to the building of an interior electromagnetic field within the Bi₄O₅Br₂/Mn_xZn_1-xFe₂O₄ heterojunction. Meanwhile, the constantly producing and migrating h⁺ and ·O₂^? were the main active components. In particular, the results of the saturation magnetization tests and magnetic recovery experiments revealed that the magnetic composite photocatalyst can be recovered effectively. The results of the removal rate of RhB remaining at 85.2% after five uses reflected the advantages of the stability of the Bi₄O₅Br₂/Mn_xZn_1-xFe₂O₄ photocatalyst. In brief, this paper presented an original idea to develop a novel composite magnetic photocatalyst and research the enhancement mechanism of photocatalysis.     

Influence of the SiC matrix introduction time on the microstructure and mechanical properties of Cf/Hf0.5Zr0.5C-SiC ultra-high temperature composites

C_f/Hf_0.5Zr_0.5C-SiC composites were prepared by introducing Hf_0.5Zr_0.5C matrix (11 cycles) and SiC matrix (9 cycles) into the carbon cloth preform through precursor impregnation and pyrolysis (PIP) process. The influence of the introduction time of SiC matrix on the microstructure and mechanical properties of C_f/Hf_0.5Zr_0.5C-SiC composites was studied, and the results show that with the increase of the PIP cycles of the SiC matrix introduced before Hf_0.5Zr_0.5C matrix, the composite open porosity decreased, and the flexural strength and modulus presented an obvious upward trend. CS45 sample, which has 4 cycles of PIP SiC introduced in advance, has the highest flexural strength, flexural modulus and interfacial shear strength of 402.73 ± 35.73 MPa, 56.92 ± 3.97 GPa and 100.88 ± 7.79 MPa, respectively. Hf_0.5Zr_0.5C matrix has a loose and porous structure, so when more SiC matrix was introduced in advance, its covering effect on the surface of fibers led to less intra-bundle pores and thusly denser composite structure, and due to the compactness of SiC matrix, better overall bonding of fiber, interface and matrix was achieved, as well as better load transfer effect, which led to obvious interfacial debonding and cracking based on the in-situ SEM observation during flexural tests. While in the sample without pre-introduced SiC, the cracking occurred mainly between the interface and porous matrix and the overall performance of the material was poor.